Hosein Aalidadi; Zahra Karimi; Aliakbar Dehghan; Hamed Mohammadi; Maryam Paydar
Abstract
Background and Purpose : Heavy metals are among the most critical contaminants in drinking water, owing to their stability and accumulation capability in living tissues and the food chain. Consequently, this study was conducted to determine the carcinogenic and non-carcinogenic risk assessment indices ...
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Background and Purpose : Heavy metals are among the most critical contaminants in drinking water, owing to their stability and accumulation capability in living tissues and the food chain. Consequently, this study was conducted to determine the carcinogenic and non-carcinogenic risk assessment indices for heavy metals in the water sources of Torbat-e Jam City in 2023.Materials and Methods : Samples were collected from 16 groundwater sources and the surrounding soil of Torbat-e Jam City during the summer and autumn of 2023. Concentrations of five heavy metals - arsenic, mercury, lead, cadmium, and copper - were measured using a Varian atomic absorption spectrometer. Finally, the health risk levels for three different groups were calculated using indices provided by the Environmental Protection Agency (EPA) of the United States.Results: The average concentrations of heavy metals in water during summer were as follows: arsenic: 0.0027 ± 0.0035 mg/L, mercury: 0.00019 ± 0.00035 mg/L, lead: 0.0011 ± 0.0023 mg/L, cadmium: 0.0002 ± 0.0002 mg/L, and copper: 0.0046 ± 0.0078 mg/L. In autumn, the concentrations were arsenic: 0.0082 ± 0.0081 mg/L, mercury: 0.0018 ± 0.0008 mg/L, lead: 0.0056 ± 0.0058 mg/L, cadmium: 0.00084 ± 0.00083 mg/L, and copper: 0.0091 ± 0.0068 mg/L. In soil, the concentrations were arsenic: 0.011 ± 0.053 mg/L, mercury: 0.0086 ± 0.0068 mg/L, lead: 0.131 ± 0.186 mg/L, cadmium: 0.0002 ± 0.00047 mg/L, and copper: 0.12 ± 0.24 mg/L. The study found the non-carcinogenic risk levels of the examined heavy metals to be low. However, the carcinogenic risk level for arsenic was very high in both seasons, for cadmium was moderate in autumn, and for the other elements, it was within the standard limits.Conclusion : Given the high carcinogenic risk of arsenic for women, men, and children in both summer and autumn, continuous monitoring of arsenic levels should be a priority for regulatory agencies.
Shayesteh Keivan; Mehran Khojasteh; Niayesh Shayesteh; MohammadJavad Khani; Farzad Zahmati; Vahid Vahid fard
Abstract
Background & objective: Balkhli River, which flows into Yamchi Dam, is the main supplier of drinking water in Ardabil City. This research aims to investigate the effect of the Ghaynarjeh Spring on Balkhli River based on surface waters quality indices.Materials & Methods: First, monthly monitoring ...
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Background & objective: Balkhli River, which flows into Yamchi Dam, is the main supplier of drinking water in Ardabil City. This research aims to investigate the effect of the Ghaynarjeh Spring on Balkhli River based on surface waters quality indices.Materials & Methods: First, monthly monitoring and analysis of Ghaynarjeh spa spring (station 1), river before acceptance and after acceptance of spring water (stations 2 and 3) was done for one year. Despite the low discharge of the spring compared to the river, The concentration of some cations and anions in the river increased greatly. In this article, by determining IRWQISC as the surface water quality index of Iran and NSFWQI as an international index, the water quality for three stations was determined.Results: The results showed that the quality of the river water after entering the spring water was degraded; In other words, the IRWQISC index of the quality of the river's water quality decreased from relatively good to average. Due to the presence of about 2,000 ppb of arsenic, about 7,000 ppb of iron and about 2,500 ppb of manganese in Ghaynarjeh Spring of Nir City, Therefore, the IRWQIST index was also considered in this research. As a result of entering the spring into the river, the river's toxicity index dropped two levels from a relatively good condition to a relatively bad one.Conclusion: Considering the high impact of ghaynarjeh spring on the quality of Balkhli Chai River from the perspective of IRWQISC and especially IRWQIST indicators and considering the importance of Balkhli Chai River in supplying drinking water in Ardabil city, the necessity of purifying the spring water before entering the Balkhli Chai River is quite evident.
Samira Abduolrahimi; Ali Akbar Safari Sinegani
Abstract
Background and Purpose: The biological pollution of landfill sites for urban waste is a crucial concern. This study aims to investigate the resistance of bacteria in contaminated soils at waste burial sites against heavy metals in Hamadan.Materials and methods: The physical and chemical characteristics ...
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Background and Purpose: The biological pollution of landfill sites for urban waste is a crucial concern. This study aims to investigate the resistance of bacteria in contaminated soils at waste burial sites against heavy metals in Hamadan.Materials and methods: The physical and chemical characteristics of soils were examined, and the total amounts of metals such as copper, lead, zinc, and cadmium were measured. Additionally, pollution load index (PLI), average pollution index (PIavg), and pollution degree (Cdeg) were estimated and analyzed. Furthermore, the percentage of stable bacteria resistant to copper, lead, cadmium, and zinc in the NA culture medium was studied by measuring the logarithm of microorganism abundanceResults: Among the mentioned sites, the soil surrounding the leachate lagoon exhibited the highest levels of organic carbon, available phosphorus, and potassium. The PLI and PIavg indices for virgin soil were below one, indicating that this soil was not polluted. However, these indices were above one for the other five sites, indicating pollution. The intensity of soil pollution in these sites exceeded the permissible limit. The logarithm of population for fungi, actinomycetes, pseudomonas, and enterobacters was highest in the new rubbish landfill, with values of 5.35, 5.28, 6.13, and 5.98, respectively. The percentage of bacteria resistant to lead was 100% in all sampled soils, but in the leachate, it was lower than 64%.Conclusion: Overall, the percentages of bacteria resistant to copper, zinc, and cadmium in the new rubbish landfill site were higher compared to other sites, which may be attributed to the landfilling of urban waste in the soil.
Behnam Pardakti; Hossein Pirkharrati; Farrokh Asad Zadeh
Abstract
Background and Purpose: In this study, heavy metals in the soil around theZanjan city, by using indicators of pollution, carcinogenic and non-carcinogenicrisk and determining the origin by using statistical methods.Materials and Methods: In this study, 30 soil samples were taken from a depthof 0-20 cm ...
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Background and Purpose: In this study, heavy metals in the soil around theZanjan city, by using indicators of pollution, carcinogenic and non-carcinogenicrisk and determining the origin by using statistical methods.Materials and Methods: In this study, 30 soil samples were taken from a depthof 0-20 cm and analyzed based on the method of acid digestion by inductioncoupled plasma spectroscopy.Results: The enrichment factor for zinc and cadmium was in the extremeenrichment category with an average of 42.1 and 34.5, respectively, and theland accumulation index for cadmium was in the high pollution category withan average of 2.8. Spatial changes of the index of pollution load and modifieddegree of pollution showed that the intensity of pollution increased nearthe industrial centers and the linear regression between the ecological riskand the median coefficient of the medium effect range (R2=0.903) showedthat 76% of the samples They are in the possibility of toxicity. Cadmium hadthe highest risk in children and adults with an average non-carcinogenic riskindex of 2 and 0.5, especially exposed to skin absorption with an average of0.5. It shows the risk of more cancer diseases. The result of determining theorigin and contribution of heavy metals with the help of statistical evaluationsshowed that lead, zinc and cadmium are the result of human activities andchromium, copper and arsenic are the result of the combination of human andearth-born activities. have gathered in the areaConclusion: In order to reduce the negative environmental effects of heavymetals in the soil of the study area, measures such as reducing the entry ofpollutants into the soil and refining polluted Soil.
Sakineh Rostami Tarzm; Farid Gholamreza Fahimi; Reza Amir Nezhad; Aptin Rahnavard; Ahmad Tavana
Abstract
AbstractIntroduction & Purpose: Gold Mining companies are one of the industries that if not properly act in accordance with the sustainable development goals, they will cause a lot of environmental contamination in the environment. In these factories, tailings dams are places where effluents and ...
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AbstractIntroduction & Purpose: Gold Mining companies are one of the industries that if not properly act in accordance with the sustainable development goals, they will cause a lot of environmental contamination in the environment. In these factories, tailings dams are places where effluents and tailings materials from gold mining factories are collected and stored, and if not properly controlled and monitored, they can be a significant source of cyanide and heavy metals contamination. In this study, cyanide and heavy metals contamination of groundwater, soil and tailings of Takab gold mine were studied.Methods: In this descriptive cross-sectional study, 19 stations were selected for sampling of piezometric wells, soils around the mine, and tailings dam of the Takab gold mine during a one-year period. Water samples were transferred to the laboratory after stored at 4 °C. The Heavy metals in water samples, soil, and tailings were measured by Atomic Absorption Spectrophotometry (AAS) method.Results: The amount of cyanide, mercury and arsenic were measured in the range of 0-105, 0-83.7 µg L-1 and 0-120.4 mg L-1 in water samples, respectively. Also the amount of these contaminants (cyanide, mercury and arsenic) in soil samples were in the range of 37.02 - 58 mg kg-1, 0 - 25.6, and 27.6 - 420 µg kg-1, respectively. Conclusion: The results showed that, there was no significant difference in the mean concentration of arsenic in the water samples of the studied wells. But in the case of mercury and cyanide, the studied wells have a significant difference. Tailings samples had the highest concentration of cyanide and heavy metals, and had significant differences with soil and water samples.
Mohammad Ebrahim Fazel Valipour
Abstract
AbstractBackground and Aim: Heavy metals contamination of soils is one of the main environmental problems. Heavy metals are considered as one most dangerous groups of pollutants because of their toxicity and stability. The biological and ecological importance of heavy metals is due to their characteristics ...
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AbstractBackground and Aim: Heavy metals contamination of soils is one of the main environmental problems. Heavy metals are considered as one most dangerous groups of pollutants because of their toxicity and stability. The biological and ecological importance of heavy metals is due to their characteristics of polluting, their toxicity, persistence and bioaccumulation. The aim of this study was to investigate the spatial distribution of heavy metals in region Dehnow Shandiz (North West of mashhad).Materials and Methods: In the present study, 20 soil samples (10-30 cm depth) collected and total concentration of As, Cd, Co, Cr and Ni were measured using Atomic absorption spectrophotometer device. Also, some other soil properties including PH, Organic carbon, CEC and soil texture proportions were measured.Results: The results showed that the average concentrations of As, Cd, Co, Cr and Ni in the study area were 10.87, 0.26, 14.8, 56.6 and 68.2 mg/kg respectively. Also the results of statistical analysis showed that the standard deviations of As, Cd, Co, Cr and Ni in the study area were 1.97, 0.16, 1.32, 19.47 and 17.39 respectively.Conclusion: The results indicate that the average concentration of Ni in the soil of study area were higher than the standard of the Environmental Protection Organization of Iran and As, Cd, Co and Cr were lower than the standard. The presence of serpentinite soils has increased the concentration of nickel in the region.Document Type: Research article
Ahmad Khoshbin; Alireza Pourkhabbaz
Abstract
Background & objectives: One of the major global concerns about the environment is the pollution of aquatic ecosystems by heavy metals. These elements contaminate aquatic environments and accumulate and concentrate through bioaccumulation in the tissues of living organisms at higher levels of the ...
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Background & objectives: One of the major global concerns about the environment is the pollution of aquatic ecosystems by heavy metals. These elements contaminate aquatic environments and accumulate and concentrate through bioaccumulation in the tissues of living organisms at higher levels of the food chain consumed by humans. In this study, the concentrations of three heavy metals, lead, nickel and cadmium, in the muscle tissue of two species of fish Otolithes ruber and Sphyraena forsteri in the fishing ports of Konarak and Pozm were investigated. Material & Methods: 36 fish samples were collected from Konarak and Pazm ports. After preparation of the samples by acid digestion, the concentrations of heavy elements lead, nickel and cadmium were measured by Contr-AA-700 atomic absorption spectrometer. Data were analyzed using SPSS software (version 20) and ANCOVA and Pearson correlation tests at a significance level of 0.05%. Results: According to the results of the study, there was no significant difference between the amounts of lead, nickel and cadmium in the muscle tissue of Otolithes ruber and Sphyraena forsteri (P> 0.05). The average concentrations of heavy metals lead, cadmium, and nickel in the muscle of fish caught from Konarak port were higher than the samples of Pozm Bay. Also, the concentrations of heavy metals lead, nickel and cadmium in Sphyraena forsteri fish were lower than those of Otolithes ruber samples. Conclusion: The results of the present study showed that the levels of lead and cadmium in the muscle tissue of the studied fish were lower than the standards of the US Food and Drug Administration, the UK Department of Fisheries and Agriculture, the World Food and Agriculture Organization and the US Environmental Protection Agency. The concentration of nickel in the muscle of the studied fish was higher than the permissible limit of the World Health Organization.
Ghasem Ranjbar; Ali Asghar Najafpoor; Ali Akbar Dehghan
Abstract
Background and Objective: The main and most important way for heavy metals to enter human body is eating food. Given that vegetables are among main food sources. For this purpose, in this study heavy metals concentrations (lead, cadmium, Arsenic and mercury) in water and wastewater used, soil and vegetables ...
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Background and Objective: The main and most important way for heavy metals to enter human body is eating food. Given that vegetables are among main food sources. For this purpose, in this study heavy metals concentrations (lead, cadmium, Arsenic and mercury) in water and wastewater used, soil and vegetables of Kashafrood margin River farms are investigated. Materials and Methods: In this in vitro study, 54 samples of three vegetable types and 18 water and wastewater samples and 18 soil samples were taken from three farms (one control and two case farms) in two consecutive months. The case farms were selected in Kashafrood River vicinity, where flow treatment plants municipal sewage and wastewater in Mashhad city. After preparation, samples acid digestion action was performed according to standard methods (3030 F Standard Method for water and vegetables – 3050 B EPA for soil). Atomic absorption device (spectrometry) was used to determine the concentration of heavy metals in samples and SPSS and Excel software were used to analyze the data. Finally, the information obtained was compared with national and international standards. Results: The mean concentrations of heavy metals (lead, cadmium, arsenic and mercury) in water, soil and vegetable samples were different and varied in time and place. Among the selected vegetables, dill samples, among farms, farm 2 and among months June illustrated most polluted one, and of the heavy metals in the samples, lead had highest concentrations. Conclusion: Heavy metal concentrations in soil and water samples were within national and international standard range, while concentrations of these metals in some vegetable samples exceeded national and international levels, which may be due to other factors, however, the use of standard effluent for agricultural irrigation requires control measures and the performance of relevant machinery duties. Keywords: Vegetables, Kashafrood, Heavy Metals
Mohammad Saleh Ali Taleshi; Mazaher Moeinaddini; Sadat Feiznia; Reza Shahbazi; Stefania Squizzato
Abstract
Background and purpose: Atmospheric dust particles play a significant role in the transfer of chemical elements released from industrial and urban sources. So that the contaminants attached to these particles, can be transported over long distances and are as a function of meteorological conditions, ...
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Background and purpose: Atmospheric dust particles play a significant role in the transfer of chemical elements released from industrial and urban sources. So that the contaminants attached to these particles, can be transported over long distances and are as a function of meteorological conditions, the physical and chemical properties and nature of surface. The aim of this study was to evaluate the metal richness and degree of heavy metal contamination in atmospheric deposited dust in Tehran. Material and methods: Atmospheric dust samples were collected from eight locations in Tehran in 2018. Heavy metals (Pb, Zn, Cu, Ni, Cr, Mn and Al) were analyzed in dust using ICP-MS. Metal richness and degree of contamination were determined using Enrichment Factor (EF), Geoaccumulation Index (Igeo), degree of Contamination (Cd) and modified degree of contamination (mCd). Paired t-test, Pearson correlation and Hierarchical cluster analysis (HCA) were also used for analysis. Results: The mean concentration trend of elements in the warm and cold seasons was similar as Al>Zn>Mn>Pb>Cu>Cr>Ni. Results of enrichment factor index in atmospheric deposited dust showed that Pb and Zn in warm season and Pb and Cu in cold season were highly enriched. Paired t-test results showed a significant difference between Cu and Cr between seasons. Cluster analysis also showed Al of natural origin and other elements of anthropogenic origin. Conclusion: The results of this study showed that atmospheric deposited dust particles of Tehran have high levels of contamination especially in cold season. Therefore, it is necessary to formulate more effective and practical policies to improve Tehran’s air quality.
Mohammad Ali Zazooli; Jamshid Yazdani; Mohsen Khanbabaee
Abstract
Background and purpose:The bulk of the waste of our country is considered to be corrupt.Compost is the best option for managing this waste component.That's why a lot of compost industries have been built in the country.Produced fertilizer compost should be in accordance with standards,so that it can ...
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Background and purpose:The bulk of the waste of our country is considered to be corrupt.Compost is the best option for managing this waste component.That's why a lot of compost industries have been built in the country.Produced fertilizer compost should be in accordance with standards,so that it can be used to improve soil quality;Therefore,the purpose of this study was to study the physical,chemical and biological properties of compost manure produced by compost industries in Mazandaran,Golestan and Guilan provinces in 2016 and compare them with standards. Materials and methods:This study is a descriptive-analytic study.Sampling and analysis of physical,chemical and biological parameters; Once a month during the 3 months of spring.Data were analyzed using SPSS16 statistical software. Results:The results showed that pH, particulate matter, phosphorus,percentage of foreign matter and heavy metals in Babol,Rasht and Aq Qala samplers were lower than standard standards of Iran,WHO and Guttos theory.In terms of moisture and C/N it is compost grade 2.For example,in terms of carbon dioxide,organic matter and nitrogen are in the compass grade I and Iran's Gotthes theory and are acceptable.In terms of fecal coliforms and Salmonella in Class A, it is considered to be in Class B leech seed. Conclusion:This study showed that the quality of compost produced is in grade 2 and therefore, in order to achieve grade 1 compost,measures such as separation at source and more principled utilization of the fertilization process are needed.
Hassan Malvandi; Nasrin Hassanzadeh
Abstract
Background and purpose: Evaluation of concentration and degree of heavy metal contamination in rivers based on sediment contamination indices is one of the important issues in ecotoxicology research. Therefore, the purpose of this study was to measure the heavy metal concentrations in the sediments of ...
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Background and purpose: Evaluation of concentration and degree of heavy metal contamination in rivers based on sediment contamination indices is one of the important issues in ecotoxicology research. Therefore, the purpose of this study was to measure the heavy metal concentrations in the sediments of the Siahrood River and to assess the health risk of these pollutants. Another purpose was to determine the status of the river in terms of contamination and non-contamination for ecotoxicology studies. Materials and Methods: Acid digestion method was used to prepare the samples. Then the concentrations of Cr, Fe, Zn, As, Se, Ni, Co, Al and Mn were measured using ICP-OES. Pollution and ecological risk indices were also calculated. Results: The mean concentrations of chromium, iron, zinc, arsenic, selenium, nickel, cobalt, aluminum and manganese were 33.02, 7309.82, 42.61, 13.15, 13.36, 12.88, 6.58, 159.28 and 384.51 µg/g dw, respectively. Most of the studied elements were in the first category of pollution assessment indices. Conclusion: The results based on contamination indices and comparison with sediment quality guidelines showed that concentrations of Cr, Se and As are of concern and could potentially be a threat to the health of organisms. For ecotoxicology studies, this river is considered to be relatively contaminated in terms of Cr, Se and As and non-contaminated for other studied elements. However, further studies and monitoring of pollutants in this ecosystem are essential for making proper and effective management decisions.
Reyhane Dehghan; Ahmad Rafiepoor; Seyed Hossein Nejad Sajadi
Abstract
Background and purpose: Heavy metals can be serious threat to food security because of the ability to accumulte in the body of fish. Therefore, considering the important role of fish play in human nutrition, the concentration of heavy metals, especially in the edible part of the fish, is necessary. Materials ...
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Background and purpose: Heavy metals can be serious threat to food security because of the ability to accumulte in the body of fish. Therefore, considering the important role of fish play in human nutrition, the concentration of heavy metals, especially in the edible part of the fish, is necessary. Materials and methods: In order to investigate the concentration of heavy metals mercury, lead and cadmium in muscle tissue of three fish species, Tuna )Scomberomoruscommerson(, Tap)Thunnustonggol (and tilapia due (Oreochromisniloticus) 20 pieces of fish were randomly collected from fish sailes in Jiroft city in winter 2017. samples were prepared by acid digestion. Data analysis was performed using SPSS 19 software, ANOVA and t-test. The presence or absence of significant difference was determined at 5% level (P <0.05). Results: The results showed that there is a significant difference between the accumulation of lead and cadmium in Tuna, Tap and tilapia muscle tissue (p <0/05) and the rate of lead accumulation in the tuna Conclusion:The concentration of mercury in the fish muscle tissue was lower than the global standard but the two metals of cadmium and lead in the tissues of Tilapia and tap were higher than the global standard. Key words: Jiroft, Cadmium, Heavy metals, food chain.
elham shahri; nematolah khorasani; gholamreza noori; ferdos kord mostafa pour; mohammad velayatzadeh
Abstract
Background & Objective: The heavy metals are considered as the pollutants which create too much problems in aquatic ecosystems for aquatics, and consequently, humans. This study aims to demystify risk assessment of some heavy metals concentrations such as Nickle, Cadmium, Lead and Zinc in the muscles ...
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Background & Objective: The heavy metals are considered as the pollutants which create too much problems in aquatic ecosystems for aquatics, and consequently, humans. This study aims to demystify risk assessment of some heavy metals concentrations such as Nickle, Cadmium, Lead and Zinc in the muscles of Otolithes ruber, Parastromateus niger, Scomberomorus commerson and Sphyraena jello fishes in 2013. Material & Methods: 96 samples from the aforementioned fishes were taken from both coastal and marine areas of Chabahar port (Oman sea). Wet Digestion method is applied to extract the considered metals from the tissues, and the concentrations of the heavy metals were measured by Atomic Absorption Spectrophotometer Younglin AAS8020. All statistical analyses were performed by SPSS (V. 17) using ANOVA along with Duncan test. Results: The results showed the highest and lowest concentrations of Cd were in Sphyraena jello and Otolithes ruber, respectively. The lowest Concentration of Pb was in Sphyraena jello. The highest and lowest concentrations of Ni and Zn were observed in Sphyraena jello and Scomberomorus commerson, correspondingly. The highest concentration of adsorbed Cd, Ni and Zn metals were measured in Sphyraena jello in the coastal area samples in children. Conclusion: Concentrations of Cd, Pb and Zn were lower than the determined proportions of FAO, WHO, UKMAFF, NHMRC and FDA. Ni concentration was higher than theGlobal Standards in Sphyraena jello.
Abbas Ali Zamani; Elham Ahmadpour; Abdolhosein Zanganeh; Younes Khosravi
Abstract
Background & objective: Cement manufacturing is the most important and influential industry in the economic prosperity of the country. However, this can be an entrance source for heavy metals to environment. The main objectives of the present study were to identify the spatial variability and main ...
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Background & objective: Cement manufacturing is the most important and influential industry in the economic prosperity of the country. However, this can be an entrance source for heavy metals to environment. The main objectives of the present study were to identify the spatial variability and main sources of heavy metals including Cr, Mn, Ni, Co, Cu, Cd, As and Zn in surface soils of the closed Kurdistan cement factory zone by conducting multivariate geostatistical analysis assisted with ArcGIS 10.2 tool. Multivariate geostatistics was used to survey the spatial distribution of studied heavy metals and their reasons in the studied area. Materials & Methods: In the present study, 88 samples of surface soils were collected in radiuses of 500, 1000, 2000 and 3000 m from the center of the cement factory from two depths of 0–15 and 15-30 cm. Results: According to the gained results, three principal factors were appeared with more than 90% of the total variance through multivariate statistical analysis for heavy metals. For mapping the distribution of the heavy metals amounts, four different models including circular, spherical, exponential and Gaussian with methods of simple Kriging, ordinary Kriging, universal and simple Co-Kriging were identified as the optimum models using ArcGIS 10.2.. The accoracy of the methods were evaluated using coefficient determination, mean absolute error, mean bias error and root mean square error. Conclusion: Heavy metals mapping confirmed that the levels of Cd, As, Pb and Cu in surface soils closed to the factory are higher than global average amount. Also, it can be mentioned that geological structure of the area plays most important role in soil pollution. However, anthropogenic activities, particularly cement plant are considered as another effective factor on soil pollution in the studied area.
Amin panah; Abdolali Karamshahi; Javad Mirzaei; Mohsen Darabi
Abstract
Background and abjective: Cement factories are considered as one of the most important pollution sources, especially heavy metals pollution. At present, Phytoremediation is known as one of the best strategies to eliminate or reduce these pollutants. In the present study the phytoremediation ability of ...
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Background and abjective: Cement factories are considered as one of the most important pollution sources, especially heavy metals pollution. At present, Phytoremediation is known as one of the best strategies to eliminate or reduce these pollutants. In the present study the phytoremediation ability of Cd, Zn, pb and Mn by nine trees species including Ailanthus glandulosa, Fraxinus rotundifolia, Robinia Pseudo Acasia, Ulmus umbraculifera, Eucalyptus microtheca, Quercus branti, Cupressus arizonica, Pinus eldarica and Cupressus sempervirens were investigated around the Ilam Cement Factory. Material and Methods: For measuring the deposition of metals in the leaves of studied species, 0.2 grams of their biomasses were separately weighed then 4 ml nitric acid (65%) was added to each sample. After 24-hincubation at room temperature, the proportions of considered metals were determined by atomic absorption spectrometry.. The obtainedresults were analyzed by SPSS 20 software usingKolmogrov-Smirnov, Leven and One-way ANOVA Tests. Results: Results showed that the amount of Cd in electro filter of factory was approximately close to the amount of Cd deposited in leaves of considered species, however; the amounts of pb, zn and mn in electro filter of factory were much more than the amounts of these three metals in leaves. The maximum and minimum accumulation of pb were related to Eucalyptus microtheca and Cupressus sempervirens respectively. In addition, the maximum and minimum amounts of deposited Mn were in Ailanthus glandulosa and Pinus eldarica respectively. The results also indicated that the maximum and minimum accumulation of Zn were in Quercus branti and Fraxinus rotundifolia respectively. Conclusion: It can be concluded from the results; the broad-leaf species are much more efficient than narrow-leaf ones in heavy metals remediation, so; it is suggested that in future development plans of green space, the broad-leaf species, especially Quercus branti, Ailanthus glandulosa Desf and Eucalyptus microtheca are more considered.
kazhal kakaei; Ali reza Riyahi Bakhtiari; Mahdi Gholamali fard
Abstract
Background and purpose: Infiltration of leachate produced by municipal solid waste into the ground water poses a serious environmental hazard due to its high content of hydrocarbons and heavy metals. The leachate is the primary source of soil and water pollution. In this paper the risk of heavy metals ...
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Background and purpose: Infiltration of leachate produced by municipal solid waste into the ground water poses a serious environmental hazard due to its high content of hydrocarbons and heavy metals. The leachate is the primary source of soil and water pollution. In this paper the risk of heavy metals discharged from leachate in to groundwater in Hamadan landfill has been assessed using Industrial Waste Management Evaluation Model (IWEM). Methods: The concentrations of heavy metals (Cu,Pb,Ni and Cd) in leachate were determined by atomic absorption spectrophotometry and the risk of these metals discharge into groundwater was assessed by IWEM using Monte Carlo analysis. Results: Based on the obtained IWEM and EPACMTP results, geosynthetic cover was recommended for this matter. Conclusion:The most appropriate option for groundwater protection in Hamadan landfill was recommended to be geosynthetic cover (Composite linear). Owing to the high probability of leachate infiltration into groundwater, there is need to be made stricter management decisions in this regard. Also, it is necessary that IWEM is used for prevention of leachate infiltration into groundwater.
Soheil Sobhanardakani; Lobat Taghavi
Abstract
Background & Objective: Nowadays due to the environmental pollution, health risk of foodstuffs consumption especially citrus species as an integral part of human diet has become a serious challenge. Therefore, this study was carried out for analysis and health risk assessment of As and Zn in some ...
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Background & Objective: Nowadays due to the environmental pollution, health risk of foodstuffs consumption especially citrus species as an integral part of human diet has become a serious challenge. Therefore, this study was carried out for analysis and health risk assessment of As and Zn in some widely used citrus samples marketed in Hamedan city in 2015. Materials and Methods: In this analytical study, 48 samples of citrus species (orange, grapefruit, lemon and tangerine) were randomly collected from four wholesale centers of Hamedan city. After samples preparation using acid digestion method, the concentrations of elements in samples were determined using inductively coupled plasma optical emission spectrometry (ICP–OES) in three replications. the gained experimental results were analyzed by SPSS 20 software using Shapiro-Wilk Test, One Sample T Test, one-way ANOVA and Pearson’s Correlation Coefficient. Results:The results showed that the maximum mean concentration (mg/kg) of As and Zn were 0.09±0.07, and 0.26±0.09 for grapefruit and lemon samples respectively. Also the computed health risk assessment showed that there is no potential risk for children and adult to consume the studied citrus. Conclusion: Although based on the obtained results, controlled consumption of studied citrus species has not adverse effect on the consumers’ health, due to the increased use of agricultural inputs especially phosphorus fertilizers, sewage sludge and wastewater by farmers and orchardists, regular periodic monitoring of chemical pollutants such as pesticides and other toxic metals (Hg, Pb, Cd and Cr) content are recommended for food safety especially in imported foodstuffs.
Majid Mirzabeygi; Abbas Abbasnia; Mojtaba sajadi; Javad Salimi; Mojtaba sajadi; Esmail harasi; Amir Hossein Mahvi
Abstract
Background & Objective: Having an access to safe drinking water, which is considered as one of the health indicators by World Health Organization (WHO), has great importance for relevant authorities of different communities. Thus this study aimed to determine amounts of heavy metals and compare them ...
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Background & Objective: Having an access to safe drinking water, which is considered as one of the health indicators by World Health Organization (WHO), has great importance for relevant authorities of different communities. Thus this study aimed to determine amounts of heavy metals and compare them with national and international standards. Materials & Methods: In this cross sectional study, drinking water samples were taken from 41 main drinking water supplies in villages of Torbat-e Heydariyeh city according to the standard method and transferred to the laboratory. These samples were analyzed by mean of atomic absorption spectrophotometer (AA240FS).Finally, obtained data were analyzed using Arc-GIS (v. 10.3) and excel (v.2010) softwares. Results: The attained results revealed that the mean concentrations of metals including Cadmium, lead and Chromium were (0.59±0.17), (1.8±1.7) and (33.5±33.4) mg/l, respectively, in drinking water wells of rural regions of Torbat-e Heydariyeh . These amounts were in optimal ranges. While chromium concentrations were more than recommended permissible levels of WHO and national standards in 11 villages. Conclusion: The mean concentrations of measured metals were lower than the recommended permissible levels by WHO in more cases of considered wells in villages of Torbat-e Heydarieh=. However, forregions in which the concentrations of heavy metals do not meet the standards, a comprehensive study is recommended to determine the heavy metal-related diseases in dry and wet seasons.
Soheil Sobhanardakani; Bahareh Babaei
Abstract
Background & Objective: Toys are integral part of children’s developmental processes. Besides providing entertainment to children, toys also serve as educational materials for them. Chemical exposure to children, from toys, is an emerging concern. Therefore, quality control of toy is very important. ...
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Background & Objective: Toys are integral part of children’s developmental processes. Besides providing entertainment to children, toys also serve as educational materials for them. Chemical exposure to children, from toys, is an emerging concern. Therefore, quality control of toy is very important. The aim of this study was examined heavy metals (As, Pb, Cd and Cr) content within the plastic children’s toys marketed in Hamadan city in 2015.Materials and Methods: Totally 30 specimens of toy were collected from market basket of Hamadan City. After preparation and processing the samples in the laboratory, the concentration of metals in samples were determined using atomic absorption spectrophotometer (AAS). Also, all statistical analyses were performed using the SPSS statistical package. Results: The results showed that the maximum mean concentrations of metals in domestic production and imported plastic toys were 6.20±5.41 and 7.58±2.12 mg/kg for Cr and Pb, respectively. Also the mean concentrations of metals in all samples were lower than Iranian National Standards Organization and European Commission permissible limits. Conclusion: Although the results showed that mean concentrations of metals in children’s toys were lower than ISIRI and CEN permissible limits, but as regards the chewing, licking and swallowing behavior of children is a common source of metals exposure, acting quickly by adopting policies to protect and educate consumers about the risks posed by plastic made toys needs a special attention which could help protect children’s lives especially in Iran.
R. Rezaei Malidareh; M. Shokrzadeh; B. Khasi; S. Rouhi4; F. Zaboli
Abstract
Background & objective:The processes of cooking and also washing reduce the amount of heavy metals in rice. So identify the best method of cooking and washing is essential to reduce heavy metals. The aim of this study is to evaluate the remaining cadmium and lead after cooking and washing processes ...
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Background & objective:The processes of cooking and also washing reduce the amount of heavy metals in rice. So identify the best method of cooking and washing is essential to reduce heavy metals. The aim of this study is to evaluate the remaining cadmium and lead after cooking and washing processes in Tarom rice in Qaemshahr city. Materials & Methods:Qaemshahr city was divided into five regions and of each region; three rice samples were collected, randomly. The concentration of lead and cadmium were evaluated in 75 raw rice samples, washed by water, cooked, rinsed rice and Kateh. Results were analyzed using software SPSS.18 and t-test student, Analysis of variance (ANOVA) and Duncan's post hoc. Results: According to t-test Student test, amount of lead and cadmium in rice was higher than the international and Iran standards. The minimum amount of cadmium was in the rinsed rice method (0.19 ± 0.08) and lead was in the washed by water method (0.87 ± 0.3). ANOVA showed that there was a significant difference between concentrations of cadmium and lead in samples of rice in different regions (p <0.05).Duncan test also showed that the average of the amounts of cadmium and lead in raw samples had a significant difference with all samples, and residue of these metals in raw rice was more than other samples (p <0.05). Conclusion: The amount of heavy metals in studied rice samples was higher than the standard limit. The minimum amount of metals was observed in the rinsing and washing methods. As regards that contamination in planted ricesnear industrial wastewater was higher than the others, So planting rice in areas closing to the industrial factories should be prevented, and best methods for rice cooking should be trained.