Abolfazl Rahmani Sani; Ahmad Hosseini Bandehgharaei; Mahsa Naeemi; Ameneh Navidzadeh; Elham Agheli
Abstract
Background and aim:Antibiotics are a category of organic pollutants that can cause serious environmental problems through their disposal and uncontrolled release to the environment. The purpose of this study was to investigate the removal of sulfadimethoxine from aqueous solutions using carbon ...
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Background and aim:Antibiotics are a category of organic pollutants that can cause serious environmental problems through their disposal and uncontrolled release to the environment. The purpose of this study was to investigate the removal of sulfadimethoxine from aqueous solutions using carbon nanotubes.
Materials and Methods:The present work was an experimental study in which the effects of different parameters, such as PH, contact time, doses of carbon nanotubes, and different concentrations of sulfadimethoxine, on the removal of antibiotic from solutions were examined. All experiments were carried out in a 100-mL reactor at laboratory temperature (24 ± 2 ° C) using a magnetic stirrer at 350 rpm.
Results:The results showed that the maximum removal efficiency (94.5%) was occurred at pH = 6, adsorbent dosage 0.04 g, contact time of 30 min, and initial concentration of 20 mg/L. The findings on the effect of pH showed that the adsorption capacity increases with increasing pH, and at pH = 6, it reaches its maximum and then decreases again. The extent of removal was increased by increasing the dose of carbon nanotubes and the optimum amount for initial concentration of 100 mg/L (50 mL) was 0.04 g. The amount of absorption increased with increasing contact time and the maximum absorption occurred when the contact time was 30 min. The sulfadimethoxine antibiotic isotherm followed the Langmuir isotherm model (R2 = 0.9800) and the pseudo-second-order kinetic model (R2 = 0.9937).
Conclusion: The results showed that carbon nanotubes have a high potential for removal of sulfadimethoxine from aqueous solutions, due to its properties like its high surface area.
Ali Naghizadeh
Abstract
Background an Objectives: Natural organic matters because of production of disinfection by products such as trihalomethanes, which are often carcinogenic disinfection, are of particular importance. Carbon nanotubes due to large surface area, and many other applications, are effective adsorbents for the ...
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Background an Objectives: Natural organic matters because of production of disinfection by products such as trihalomethanes, which are often carcinogenic disinfection, are of particular importance. Carbon nanotubes due to large surface area, and many other applications, are effective adsorbents for the removal of natural organic matter. The present study aimed to investigate the removal of natural organic compounds from aqueous solution by single-walled carbon nanotubes and kinetics and equilibrium adsorption process. Methods: in present study, single wall carbon nanotubes used for removal of natural organic matters from aqueous solution. Different variables such as pH of zero point of charge, pH and different concentration of natural organic matters were investigated. Results: pH survey show that with decreasing pH adsorption capacity increased also pH of zero charge was 6.7. Adsorption capacity of single wall carbon nanotubes for initial concentration of natural organic matters of 10, 5 and 3 mg/L were 66.24, 40.63 and 29.77, respectively. Conclusion: Single-walled carbon nanotubes due to features such as high surface area have great potential for the removal of natural organic matter from aqueous solution