Fahimeh Sharifan; Ali Shahidi; Abbas Khashei
Abstract
Background& objective: The hexavalent chromium is a toxic and water-soluble heavy metal that is absorbed and stored through the digestive system and through the skin in the human body. That amount is exceeded in drinking water in Birjand. So the purpose of this studies, Process about remove the hexavalent ...
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Background& objective: The hexavalent chromium is a toxic and water-soluble heavy metal that is absorbed and stored through the digestive system and through the skin in the human body. That amount is exceeded in drinking water in Birjand. So the purpose of this studies, Process about remove the hexavalent chromium by using from pine fruit powder, carbon and compare to each other. Methods: In this research, for Calculate removal efficiency (Re), Parameters of contact time, pH, adsorbent dose, initial Cr (VI) concentration and Temperature was studied. Experiments were intermittently performed in batch reactor on Shaker. Results: The results showed that the absorption of chromium significantly depends on the pH of the solution and the absorption rate in the range of 3 for powder and 1 for carbon was achieved when the pH of the solution. The maximum removal of Cr (VI) for pine fruit powder is 96/5 % and for activated Carbon Pine Cones is 93/958%. The results indicate that the soluble chromium ions through the absorbent used in this study, as well as follow the Langmuir isotherm model. Conclusion: The most remove of the hexavalent chromium happened by pine fruit powder and Pine cones can be used as an effective and inexpensive method to remove of the hexavalent chromium from contaminated wastewater.
Golamreza Mousavi; Ahmad Allah-Abadi; Yahya Jalili Darbandi
Abstract
Background & Objectives: With the increasing trend of imports and exports in the country, the number of transport vehicles is also growing at the customs gates across the world. This causes the wastewater disinfection gates to increase in number at the borders of a country. Du to a cationic detergent ...
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Background & Objectives: With the increasing trend of imports and exports in the country, the number of transport vehicles is also growing at the customs gates across the world. This causes the wastewater disinfection gates to increase in number at the borders of a country. Du to a cationic detergent called Benzalkonium chloride, the wastewater produced in these places is not biologically treatable. Therefore, advanced oxidation methods are considered as a viable option for treating the wastewater. In aspect-oriented programming (AOP), catalytic ozonation with activated carbon is regarded as an efficient method of disinfection. The present study aimed to determine the optimal conditions of using activated carbon produced from agricultural waste and activated with NH4CL as a heterogeneous catalyst with Ozone. Methods: In this study, the chemical quality of wastewater was evaluated at the disinfection customs gate of Lotf Abad Using single and catalytic ozonation by NH4Cl-induced activated carbon obtained from agricultural waste as the base material, COD removal was performed in a 200cc continuous reactor. The studied variables were pH, catalyst concentration and the reaction time. In the catalytic ozonation, single absorption and the synergistic effect of the catalysts were also investigated. Results: According to the results of the present study, with the ozone dose of 1 mg/min of alkaline pH in 30 minutes, single ozonation was able to remove only 39.7% of COD while catalytic ozonation with 0.1 g/L of carbon catalyst concentration in the same condition removed 66.8% of COD creating a 13.6% of synergistic effect as well. Conclusion: Activated carbon with NH4CL could noticeably increase the oxidation with ozone. Thus, it could be used as a catalyst in the ozonation reactor in order to remove COD from wastewater. Paper Type: Research Article